Nicholson R S & Shain I. Theory of stationary electrode polarography: single scan and cyclic methods applied to reversible, irreversible, and kinetic systems. Anal. Chem. 36:706-23, 1964
نویسنده
چکیده
The theory of cyclic voltammetry is presented for chemical reactions coupled with electron transfer reactions. A numerical method is described for solving integral equations derived from the appropriate boundary value problems. New correlations make it possible to characterize unknown systems by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan. [The SCI® indicates that this paper has been cited over 895 times since 1964.]
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